Using numerical simulations we study the formation of thick films. We
expect that the gross features of their morphology result from the com
bination of a few number of general processes. For instance, this coul
d be the case of passive films formed on a lithium surface. Starting f
rom this example a model of growth on a two dimensional lattice is pro
posed. It is based on the existence of chemical reactions which occur
in the presence of a poison. It differs from the popular Eden model by
the fact that the evolution probability of one site on the lattice de
pends on the local structure of the layer in formation. The numerical
simulations show that different morphologies may appear for the bulk p
art of the layer. We hope that this model might be useful to describe
a large class of growth processes in which the formation of a thick fi
lm is initiated by chemical reactions. Copyright (C) 1996 Elsevier Sci
ence Ltd