3'-Acetylrinderine, 3'-acetylechinatine, 3-acetylheliosupine and helio
supine were isolated from the aerial parts of Cynoglossum creticum and
characterized by mass spectrometry and H-1 and C-13 NMR. A GC-mass sp
ectrometric analysis revealed the presence of 13 alkaloids altogether,
among them the previously reported alkaloids, echinatine, rinderine a
nd 7-angeloylheliotridine, and traces of 7-senecioylheliotridine, supi
nine and trachelanthamine.