E. Vanderlinden et al., RELATION BETWEEN THE SIZE OF LAMELLAR DROPLETS IN ONION PHASES AND THEIR EFFECTIVE SURFACE-TENSION, Langmuir, 12(13), 1996, pp. 3127-3130
A closed packed system (''onion phase'') of so-called lamellar droplet
s, consisting of concentric surfactant bilayers which are separated fr
om one another by water, may be obtained by subjecting a continuous la
mellar phase to shear. We propose a model for the size of these lamell
ar droplets under shear as a function of their effective surface tensi
on. This model fits the available experimental data quantitatively and
explains the dependence of the size on surfactant volume fraction.