REACTIONS OF GLYOXAL-DERIVED IMINIUM IONS WITH UNSATURATED SILYL AND SILYLOXY REAGENTS

Authors
AGAMI C BIHAN D PUCHOTKADOURI C
Citation
C. Agami et al., REACTIONS OF GLYOXAL-DERIVED IMINIUM IONS WITH UNSATURATED SILYL AND SILYLOXY REAGENTS, Tetrahedron, 52(27), 1996, pp. 9079-9086
Citations number
16
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron → ACNP
ISSN journal
00404020
Volume
52
Issue
27
Year of publication
1996
Pages
9079 - 9086
Database
ISI
SICI code
0040-4020(1996)52:27<9079:ROGIIW>2.0.ZU;2-D
Abstract
Iminium ions derived from a condensation of glyoxal and N-methyl (R)-p henylglycinol react with allylic silanes (trimethylallyl and trimethyl methallylsilanes) and enoxysilanes (2-trimethylsilyloxypropene and 2-t rimethylsilyloxystyrene). These reactions proceed in a totally stereos elective way as evidenced by a chemical correlation and an X-Ray analy sis of a compound related to both series of experiments. Copyright (C) 1996 Elsevier Science Ltd