SYNTHESIS OF CATIONIC 4-METHOXYCYCLOHEXADIENYL)-(TRIPHENYLPHOSPHINE)IRON COMPLEXES

Authors
GUILLOU C MILLOT N REBOUL V THAL C
Citation
C. Guillou et al., SYNTHESIS OF CATIONIC 4-METHOXYCYCLOHEXADIENYL)-(TRIPHENYLPHOSPHINE)IRON COMPLEXES, Tetrahedron letters, 37(26), 1996, pp. 4515-4518
Citations number
12
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
37
Issue
26
Year of publication
1996
Pages
4515 - 4518
Database
ISI
SICI code
0040-4039(1996)37:26<4515:SOC4>2.0.ZU;2-B
Abstract
Cationic 4-methoxycyclohexadienyl)-(triphenylphosphine)iron complexes 10 form a new class of highly functionalised iron complexes which have never been described. They were obtained from neutral-substituted ta( 4)-4-methoxy-1,3-cyclohexadiene)Fe(CO)(2)PPh(3) iron complexes 9, prep ared by ligand exchange reaction under improved experimental condition s. A quaternary carbon was formed in quantitatively yield by regiosele ctive nucleophilic nitrile attack on cation 10e. Copyright (C) 1996 Pu blished by Elsevier Science Ltd