High resolution, high signal-to-noise ratio CCD spectra of the Be-shel
l star 48 Librae allowed the investigation of rapid variability in the
photospheric He I 4471 and Mg II 4481 lines. Though our sample was li
mited (51 spectra over four nights), 48 Lib has revealed itself to be
a good candidate to display multiperiodic spectroscopic variations. Th
ree frequencies, 1.86, 3.09 and 10.64 c/d, have been detected in the H
e I line and seem to be present in Mg II 4481 though this latter, stro
ngly blended in its core with a marked shell feature, is not appropria
te for this kind of study. The higher frequency 10.64 c/d has been ded
uced from a time series analysis with two methods and from a residual
analysis. It has been associated with a l = \m\=8+/-2 sectorial g mode
in the frame of non-radial oscillations. We did not succeed in findin
g in our data the most probable photometric frequency 2.49 c/d, previo
usly given by McDavid (1988) and Cuypers et al. (1989), and recently d
etected in the UV flux by Peters (1994), however this photometric freq
uency and the lower spectroscopic frequencies 1.86 and 3.09 c/d seem t
o be mutually linked.