P. Barnes et al., APPLIED CRYSTALLOGRAPHY SOLUTIONS TO PROBLEMS IN INDUSTRIAL SOLID-STATE CHEMISTRY - CASE EXAMPLES WITH CERAMICS, CEMENTS AND ZEOLITES, Journal of the Chemical Society. Faraday transactions, 92(12), 1996, pp. 2187-2196
Citations number
44
Categorie Soggetti
Chemistry Physical","Physics, Atomic, Molecular & Chemical
We show that a number of processes involved in the field of industrial
solid-state chemistry can be successfully studied in situ using a ran
ge of crystallographic and related techniques. The adaptation of relev
ant equipment to reproduce the process environment at the sample is a
crucial part of the approach. Examples are given, involving the synthe
sis of zirconia-based ceramics, hydration of cements, and dehydration
of zeolites, where successful applications of this approach have uncov
ered new structural/kinetic aspects concerning seemingly well establis
hed industrial processes.