L. Callegaro et al., ELECTROPLATED, HIGH H-C COPT FILMS - DELTA-M MAGNETOOPTICAL MEASUREMENTS, Journal of magnetism and magnetic materials, 155(1-3), 1996, pp. 190-192
Co-rich CoPt and CoPtP alloy thin films were obtained by electrodeposi
tion. Addition of a P compound to the electrolyte for CoPt deposition
induces P codeposition and improves film hard magnetic properties, rea
ching coercive forces up to 5500 Oe, with S = 0.7. To understand the
effect of P compound addition, a macroscopic characterization of inter
grain interactions in CoPt and CoPtP films of similar composition and
structure has been made by the delta M method, using longitudinal Kerr
effect as magnetization probe. delta M curves reveal exchange couplin
g in CoPt films, while CoPtP films show mainly magnetostatic interacti
ons. The creation of single-domain grains with nonmagnetic boundaries
is proposed as an explanation for the inhibition of exchange interacti
ons in CoPtP films.