K. Tankeshwar et Nh. March, RELATION BETWEEN ELECTRICAL AND THERMAL-CONDUCTIVITIES IN CHARGED CONDENSED PHASES, Physics and chemistry of liquids, 31(1), 1996, pp. 39-47
Data and simple theory is brought into contact for the ratio lambda/si
gma T for some charged condensed phases, lambda being the thermal cond
uctivity and sigma the electrical conductivity. The most extensive dat
a presented is for liquid metals and deviations from the Weidmann-Fran
z law are discussed. But the paper is also concerned with metal nitrat
es (e.g., NaNO3) and with ionized gases and dilute plasmas. Returning
to metals, cases be cited where lambda and sigma separately vary marke
dly across the solid-liquid transition, while the ratio lambda/sigma T
remains substantially constant.