DIPOLAR INTERACTION IN A BIPOLAR SYSTEM LONG-CHAIN ALIPHATIC-ALCOHOLSWITH CARBOXYLIC-ACIDS

Authors
GARABADU K SWAIN BB
Citation
K. Garabadu et Bb. Swain, DIPOLAR INTERACTION IN A BIPOLAR SYSTEM LONG-CHAIN ALIPHATIC-ALCOHOLSWITH CARBOXYLIC-ACIDS, Physics and chemistry of liquids, 31(1), 1996, pp. 63-70
Citations number
10
Categorie Soggetti
Chemistry Physical","Physics, Condensed Matter
Journal title
Physics and chemistry of liquids → ACNP
ISSN journal
00319104
Volume
31
Issue
1
Year of publication
1996
Pages
63 - 70
Database
ISI
SICI code
0031-9104(1996)31:1<63:DIIABS>2.0.ZU;2-3
Abstract
Dielectric constant of binary mixtures of some long-chain aliphatic al cohols i.e. il-propanol, n-pentanol, n-hexanol, n-heptanol and n-octan ol with propionic acid and butyric acid measured at 455 kHz and at 303 .16 K are utilised to calculate mutual correlation factor g(ab), exces s molar polarization Delta p and excess free energy of mixing Delta F- ab in those binary mixtures. The results indicate that acid-alcohol in teraction is stronger in butyric acid system than in the propionic aci d system.