High-power lasers in industrial and R&D applications raise the general
problem of reliability and degradation of optical components. A syste
matic study of nonlinear interaction of various transparent dielectric
materials as e.g. glasses, fused silica, and polymers, with laser-pul
ses in the intensity range of up to 10(13) W cm(-2) is presented. On t
he other hand, femtosecond-pulse laser processing in the visible spect
ral range (300 fs; 620 nm, similar to 2 eV) allows precise microstruct
uring of transparent dielectrics without disruption of the remnant mat
erial. Damage and ablation threshold fluences occur above 1.2 J cm(-2)
at both silicate glasses and fused silica. Two different photon absor
ption mechanisms have been observed. The first occurs during the initi
al laser pulses in the incubation range. There, multiphoton absorption
results in moderate energy volume densities. These are sufficient to
generate morphological changes and optically active defect sites (colo
ur centres) which provide a much higher absorptivity relevant fur the
second mechanism. It results in gasification without participation of
melt.