XeCl laser ablation of films of ZnS, with 200-600 nm thickness, on Si
substrates has been studied at laser fluences lower than that required
to damage the substrate material. The ZnS film ablation rate (depth o
f material removed per pulse) is observed to decrease with residual fi
lm thickness and increase with laser fluence. The fluence threshold fo
r the onset of ablation is shown to depend inversely on the initial fi
lm thickness. This behaviour is explained in terms of a thermal remova
l mechanism in which the thermal properties of the substrate play a vi
tal role in regulating the film ablation characteristics.