A comparative study of laser ablation of bulk samples of Upilex polyim
ide and low density polyethylene, which represent extremes in terms of
absorption index at the ArF laser wavelength, is reported. High Speed
Shadow photography (HSSP), Probe Beam Deflection (PBD) and Time Resol
ved Interferometry (TRI) techniques have been used to provide informat
ion about the ablation process. It is shown that HSSP allows the laser
generated shock wave and particulate products to be visualised as the
y expand away from the ablation site. PBD signals are seen to correlat
e well with the HSSP results and allow data to be obtained for an abla
tion regime in which no visible plume is observed. The TRI technique g
ives complementary, lime-space resolved, information about the nature
of the product expansion.