K. Thomsen et al., CORRELATION AND PREDICTION OF THERMAL-PROPERTIES AND PHASE-BEHAVIOR FOR A CLASS OF AQUEOUS-ELECTROLYTE SYSTEMS, Chemical Engineering Science, 51(14), 1996, pp. 3675-3683
An extended UNIQUAC model is used to describe phase behaviour (VLE, SL
E) and thermal properties (heat of mixing, heat capacity) for aqueous
solutions containing ions like (Na+, K+, H+) (Cl-, NO3-, SO42-, OH-, C
O3-). A linear temperature dependence of the binary interaction parame
ters allows good agreement with experimental data in the temperature r
ange 0-110 degrees C. Copyright (C) 1996 Elsevier Science Ltd