UNPRECEDENTED OBSERVATION OF PRONOUNCED VIBRATIONAL STRUCTURE IN CHARGE-TRANSFER ABSORPTION AND EMISSION-SPECTRA

Authors
WIERING PG VERHOEVEN JW
Citation
Pg. Wiering et Jw. Verhoeven, UNPRECEDENTED OBSERVATION OF PRONOUNCED VIBRATIONAL STRUCTURE IN CHARGE-TRANSFER ABSORPTION AND EMISSION-SPECTRA, Recueil des travaux chimiques des Pays-Bas, 115(5), 1996, pp. 303
Citations number
15
Categorie Soggetti
Chemistry
Journal title
Recueil des travaux chimiques des Pays-Bas → ACNP
ISSN journal
01650513
Volume
115
Issue
5
Year of publication
1996
Database
ISI
SICI code
0165-0513(1996)115:5<303:UOOPVS>2.0.ZU;2-7
Abstract
Two rigidly bridged electron donor-acceptor systems are reported that display discrete, intramolecular charge-transfer (CT) absorption and e mission spectra in solution at room temperature. For both the CT-absor ption is highly structured irrespective of solvent, for one also the C T-fluorescence in a nonpolar solvent is structured.