K. Sanui et al., SYNTHESIS OF HIGH-PERFORMANCE COMPOSITES BY IN-SITU POLYCONDENSATION AND THEIR MECHANICAL-PROPERTIES, Reactive & functional polymers, 30(1-3), 1996, pp. 293-298
High-performance composites of vinylpyridine-styrene copolymers and po
lyamic acid (PAA) were prepared by the so-called 'in situ polymerizati
on method'. Poly(4-vinylpyridine-co-styrene) (P4VPy-St) and poly(2-vin
ylpyridine-co-styrene) (P2VPy-St) were used as flexible matrix polymer
s. A molecular composite could be obtained from a polymer pair having
an attractive interaction such as a coulombic interaction. Their morph
ologies were observed by scanning electron microscopy (SEM); mechanica
l properties of these composites were studied by tensile tests. The PA
A content dependence of tensile strength for the composite films obtai
ned by the in situ polymerization method was investigated. The tensile
strength of the resulting composite was about 1.5 times higher than t
hat of PAA film. The coulombic interaction between the pyridine moiety
in the matrix copolymer and resulting PAA enhanced both the miscibili
ty and mechanical properties of the composites. Furthermore, a polyimi
de (PI) structure was formed by stepwise heat-treatment and greatly en
hanced the tensile strength of the composite films.