E)(TRIPHENYLPHOSPHINE)PALLADIUM(II)-ACETONITRILE(1 1)/

Authors
LONG DL XIN XQ HUANG XY
Citation
Dl. Long et al., E)(TRIPHENYLPHOSPHINE)PALLADIUM(II)-ACETONITRILE(1 1)/, Acta crystallographica. Section C, Crystal structure communications, 52, 1996, pp. 2724-2726
Citations number
7
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
52
Year of publication
1996
Part
11
Pages
2724 - 2726
Database
ISI
SICI code
0108-2701(1996)52:<2724:E1>2.0.ZU;2-L
Abstract
In the structure of the title compound, ,1-ethylenedicarbonitrilato(2- )-S,S'](pyridine-N)- (triphenylphosphine-P)palladium(II)-acetonitrile (1/1), [Pd(C4N2S2)(C5H5N)(C18H15P)].CH3CN, the Pd atom is coordinated by the two S atoms of the dimercaptoethylenedicarbonitrilate ligand ac ting as a bidentate ligand, the P atom from triphenylphosphine and the N atom from pyridine, with Pd-S distances of 2.288 (2) and 2.340(1) A ngstrom, a Pd-P distance of 2.300(1)lq and a Pd-N distance of 2.082 (3 ) Angstrom. The S-Pd-S angle is 75.35 (4)degrees.