2-(2,5-DICHLOROPHENYLHYDRAZONO)GLUTARIC ACID AND 2-(3,5-DICHLOROPHENYLHYDRAZONO)GLUTARIC ACID

Authors
ANTOLIC S KOJICPRODIC B COHEN JD
Citation
S. Antolic et al., 2-(2,5-DICHLOROPHENYLHYDRAZONO)GLUTARIC ACID AND 2-(3,5-DICHLOROPHENYLHYDRAZONO)GLUTARIC ACID, Acta crystallographica. Section C, Crystal structure communications, 52, 1996, pp. 2832-2835
Citations number
16
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
52
Year of publication
1996
Part
11
Pages
2832 - 2835
Database
ISI
SICI code
0108-2701(1996)52:<2832:2AA2>2.0.ZU;2-P
Abstract
The title compounds, C11H10Cl2N2O4, are constitutional isomers which e xhibit similar molecular geometry. The configuration about the N=C bon d is E in both molecules. The same packing pattern was found in both s tructures. Hydrogen-bonded dimers, formed around the inversion centres via O-H ... O interactions of carboxyl groups, are connected into inf inite chains. The intramolecular N-H ... Cl hydrogen bond observed onl y in the 2,5-dichlorophenyl derivative contributes to the planarity of the molecule.