NEW OPTICALLY PURE SUGAR HYDROPEROXIDES - SYNTHESIS AND USE FOR ENANTIOSELECTIVE OXYGEN-TRANSFER

Authors
HAMANN HJ HOFT E MOSTOWICZ D MISHNEV A URBANCZYKLIPKOWSKA Z CHMIELEWSKI M
Citation
Hj. Hamann et al., NEW OPTICALLY PURE SUGAR HYDROPEROXIDES - SYNTHESIS AND USE FOR ENANTIOSELECTIVE OXYGEN-TRANSFER, Tetrahedron, 53(1), 1997, pp. 185-192
Citations number
12
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron → ACNP
ISSN journal
00404020
Volume
53
Issue
1
Year of publication
1997
Pages
185 - 192
Database
ISI
SICI code
0040-4020(1997)53:1<185:NOPSH->2.0.ZU;2-E
Abstract
2-Deoxy-2-C-methylene methyl glycosides undergo oxidation with hydroge n peroxide in the presence of molybdenum trioxide as catalyst to affor d the corresponding anomeric hydroperoxides. These hydroperoxides were used as chiral oxidants of allylic alcohols and prochiral sulfides to offer moderate enantioselectivities which were, however, higher than those reported before for oxidation with optically active peroxyacids. Copyright (C) 1996 Elsevier Science Ltd