M. Canepa et al., DIFFUSION BY ATOMIC PLACE EXCHANGE IN ULTRATHIN IRON FILMS ON AG(100)- AN ION-SCATTERING SPECTROSCOPY STUDY, Surface science, 352, 1996, pp. 36-40
The surface composition of ultrathin (0-10 ML) iron films deposited on
a well defined Ag(100) substrate at 140 K has been investigated by io
n scattering spectroscopy. The data unambiguously show the occurrence
of intermixing. The concentration of Ag at the surface decreases rathe
r rapidly with the film thickness but it is still relevant (similar to
10%) even in the case of the thickest layer. The data are interpreted
in terms of an atomic place exchange between silver and incident iron
atoms at the surface of the growing film.