Cleaved MgO surfaces are characterized under ultra-high vacuum (UHV) c
onditions, by means of atomic force microscopy (AFM) and X-ray photoel
ectron spectroscopy (XPS). To obtain well-defined samples, MgO crystal
s are cleaved under dry nitrogen, prior to being quickly inserted in U
HV via a load-lock system. AFM images show 10 to 100 nm wide (100) ter
races running over distances of microns. After either adsorption or co
ntamination in UHV, cleaved MgO surfaces can be cleaned by heating sam
ples at 1200 K under an oxygen pressure > 10(-3) Pa without inducing a
ny visible change in the surface morphology. In contrast, the exposure
to ambient air strongly affects these surfaces by irreversibly produc
ing disordered similar to 10 X 10 nm(2) patches.