REACTIONS OF LASER-ABLATED IRON ATOMS WITH N2O, NO, AND O-2 IN CONDENSING NITROGEN - INFRARED-SPECTRA AND DENSITY-FUNCTIONAL CALCULATIONS OF TERNARY IRON NITRIDE OXIDE MOLECULES

Authors
ANDREWS L CHERTIHIN GV CITRA A NEUROCK M
Citation
L. Andrews et al., REACTIONS OF LASER-ABLATED IRON ATOMS WITH N2O, NO, AND O-2 IN CONDENSING NITROGEN - INFRARED-SPECTRA AND DENSITY-FUNCTIONAL CALCULATIONS OF TERNARY IRON NITRIDE OXIDE MOLECULES, Journal of physical chemistry, 100(27), 1996, pp. 11235-11241
Citations number
28
Categorie Soggetti
Chemistry Physical
Journal title
Journal of physical chemistry → ACNP
ISSN journal
00223654
Volume
100
Issue
27
Year of publication
1996
Pages
11235 - 11241
Database
ISI
SICI code
0022-3654(1996)100:27<11235:ROLIAW>2.0.ZU;2-K
Abstract
Reactions of laser-ablated Fe atoms with N2O, NO, and O-2 in excess N- 2 during condensation at 10 K produced new absorptions with N-15 and O -18 shifts that are assigned to the new ternary iron nitride oxide mol ecules NFeO, NFeO2, and N2FeO. DFT calculations of structure and isoto pic frequencies support these assignments.