It was found from the IR and UV-visible spectra, that the ion implanta
tion into polymers results in the breakage of molecular chain, creatio
n of double bonds and oxidation, which is connected with formation of
carbonyl groups. The considerable increase of the electrical conductiv
ity after the ion implantation was observed in all studied polymers. T
his increase of the conductivity was essentially caused by the increas
e of conjugated double bonds. In unpolar polymers, the increase of sur
face free energy resulting in enhancement of polarity of unpolar polym
er was found.