P. Calvi et al., THE POLAR TRANSITION OF LI-DOPED AND NB-DOPED KTAO3 - COMPARATIVE-ANALYSIS FROM HARD-PHONON RAMAN-SPECTRA, Radiation effects and defects in solids, 137(1-4), 1995, pp. 1425-1429
Raman investigations have been performed on K0.984Li0.016TaO3 and KTa0
.976Nb0.024O3 single crystals, in order to follow the peculiarities of
non-ferroelectric phonons, which may be indicative of a different evo
lution of microscopic order during the polar transition. Specific feat
ures in the Nb case confirm a ferroelectric behaviour, whereas in the
Li-doped sample the results are in agreement with a dipole glass trans
ition.