Mp. Delamare et al., COMBINATION OF CEO2 AND PTO2 DOPING FOR STRONG ENHANCEMENT OF J(C) UNDER MAGNETIC-FIELD IN MELT-TEXTURED SUPERCONDUCTOR YBACUO, Physica. C, Superconductivity, 262(3-4), 1996, pp. 220-226
A combination of CeO2 and PtO2 doping has been studied in melt-process
ed YBa2Cu3O7-x. This study was carried out using an optimized well est
ablished MTG process. The cerium-platinum doped samples exhibit a high
fishtail effect with a J(c) of 4.3 x 10(4) A/cm(2) under an applied f
ield of 1 T. Microstructural and nanostructural studies have been perf
ormed. The 211 and BaCeO3 inclusions are a few micrometers wide and th
e formation of a metastable nanocrystalline phase (Y4Ba4)Cu-8-x(Ce,Pt)
(x)O-20+delta related to the perovskite is detected. The 123 grains sh
ow no specific extended defect generated by the doping process. The re
lationship between structure and properties are discussed.