T. Braun et H. Rausch, FORMATION OF THE (ARC60)-AR-41 ENDOHEDRAL COMPLEX BY PROMPT NUCLEAR RECOILING FOLLOWING NEUTRON-IRRADIATION, Magyar kemiai folyoirat, 102(6), 1996, pp. 297-300
It is demonstrated that by the neutron irradiation of polycrystalline
C-60 in an argon gas atmosphere or of C-60 crystals containing previou
sly ab- and adsorbed argon, a stable endohedral argon compound is form
ed. The concentration of argon has been determined by instrumental neu
tron activation analysis (INAA) via the short-lived Ar-41 isotope. It
is supposed that the endohedral compound is formed by the penetration
of the argon atom into the C-60 cages; a mechanism due to the high kin
etic energy recoiling Ar-41 atoms according to the Ar-40(n,gamma)Ar-41
nuclear reaction seems the most plausible.