EFFICIENT PREPARATION AND X-RAY STRUCTURE ANALYSES OF (2R)-N-PYRUVOYL-BORNANE-10,2-SULTAM AND (2R)-N-(PHENYLGLYOXYLOYL)BORNANE-10,2-SULTAM

Citation
T. Bauer et al., EFFICIENT PREPARATION AND X-RAY STRUCTURE ANALYSES OF (2R)-N-PYRUVOYL-BORNANE-10,2-SULTAM AND (2R)-N-(PHENYLGLYOXYLOYL)BORNANE-10,2-SULTAM, Helvetica Chimica Acta, 79(4), 1996, pp. 1059-1066
Citations number
44
Categorie Soggetti
Chemistry
Journal title
ISSN journal
0018019X
Volume
79
Issue
4
Year of publication
1996
Pages
1059 - 1066
Database
ISI
SICI code
0018-019X(1996)79:4<1059:EPAXSA>2.0.ZU;2-B
Abstract
An efficient synthesis of the two title compounds is reported, as well as their X-ray crystal-structure analyses. A discussion based on ster eoelectronic considerations rationalizes the first example of a crysta lline SO2/C(O) syn-periplanar conformer of a N-acylbornane-10,2-sultam .