MAYA BLUE PAINT - AN ANCIENT NANOSTRUCTURED MATERIAL

Citation
M. Joseyacaman et al., MAYA BLUE PAINT - AN ANCIENT NANOSTRUCTURED MATERIAL, Science, 273(5272), 1996, pp. 223-225
Citations number
13
Categorie Soggetti
Multidisciplinary Sciences
Journal title
ISSN journal
00368075
Volume
273
Issue
5272
Year of publication
1996
Pages
223 - 225
Database
ISI
SICI code
0036-8075(1996)273:5272<223:MBP-AA>2.0.ZU;2-6
Abstract
Maya blue paint was often used in Mesoamerica. The origin of its color and its resistance to acids and biocorrosion have not been fully unde rstood. High-resolution transmission electron microscopy, electron ene rgy loss spectroscopy, and x-ray microanalysis studies of authentic sa mples show that palygorskite crystals in the paint form a superlattice that probably occurs as a result of mixing with indigo molecules. An amorphous silicate substrate contains inclusions of metal nanoparticle s encapsulated in the substrate and oxide nanoparticles on the surface . The beautiful tone of the color is obtained only when both the parti cles and the superlattice are present.