HEMISYNTHESIS FROM CHAETOGLOBOSIN-M .1. OBTENTION OF 2 NEW CHAETOGLOBOSINS BY INTRAMOLECULAR MICHAEL REACTION UNDER MILD BASIC CONDITIONS

Authors
BURLOT L CHERTON JC CONVERT O LARPENT C DENNETIERE B DARDOIZE F
Citation
L. Burlot et al., HEMISYNTHESIS FROM CHAETOGLOBOSIN-M .1. OBTENTION OF 2 NEW CHAETOGLOBOSINS BY INTRAMOLECULAR MICHAEL REACTION UNDER MILD BASIC CONDITIONS, Magnetic resonance in chemistry, 34(7), 1996, pp. 538-544
Citations number
13
Categorie Soggetti
Spectroscopy,Chemistry
Journal title
Magnetic resonance in chemistry → ACNP
ISSN journal
07491581
Volume
34
Issue
7
Year of publication
1996
Pages
538 - 544
Database
ISI
SICI code
0749-1581(1996)34:7<538:HFC.OO>2.0.ZU;2-C
Abstract
Under mild basic conditions, Chaetoglobosin M leads to the formation o f two new bridged chaetoglobosins with preservation of the epoxide fun ction, The structures of these new toxins are proposed on the basis of high-resolution MS and NMR data and supported by molecular modelling.