EXTRACTION OF FE(III) FROM NITRIC-ACID SOLUTIONS WITH CARBAMOYLMETHYLPHOSPHINE OXIDES AND SEPARATION OF FE(III) FROM AM(III)

Authors
PRIBYLOVA GA CHMUTOVA MK SMIRNOV IV SHADRIN AY MYASOEDOV BF
Citation
Ga. Pribylova et al., EXTRACTION OF FE(III) FROM NITRIC-ACID SOLUTIONS WITH CARBAMOYLMETHYLPHOSPHINE OXIDES AND SEPARATION OF FE(III) FROM AM(III), Radiochemistry, 38(2), 1996, pp. 139-142
Citations number
7
Categorie Soggetti
Chemistry Analytical","Chemistry Inorganic & Nuclear
Journal title
Radiochemistry → ACNP
ISSN journal
10663622
Volume
38
Issue
2
Year of publication
1996
Pages
139 - 142
Database
ISI
SICI code
1066-3622(1996)38:2<139:EOFFNS>2.0.ZU;2-4
Abstract
Extraction of Fe(III) and Am(III) from HNO3 solutions with solutions o f ditolyl(diethylcarbamoylmethyl)phosphine oxide (Tl(2)Et(2)) and diph enyl(dibutylcarbamoylmethyl)phosphine oxide (Ph(2)Bu(2)) in Fluoropol is studied. The influence of the phase contact time and concentrations of the reagent, metal, and nitric acid on the extraction and the Am/F e separation factors is examined. Conditions are found for quantitativ e recovery of americium from iron-containing nitric acid solutions wit h an Am/Fe separation factor of 10(4).