THERMODYNAMIC FUNCTIONS OF MIXING IN TRI-N-BUTYL PHOSPHATE-DILUENT SYSTEMS

Citation
Ak. Pyartman et Aa. Kopyrin, THERMODYNAMIC FUNCTIONS OF MIXING IN TRI-N-BUTYL PHOSPHATE-DILUENT SYSTEMS, Radiochemistry, 38(2), 1996, pp. 154-156
Citations number
6
Categorie Soggetti
Chemistry Analytical","Chemistry Inorganic & Nuclear
Journal title
ISSN journal
10663622
Volume
38
Issue
2
Year of publication
1996
Pages
154 - 156
Database
ISI
SICI code
1066-3622(1996)38:2<154:TFOMIT>2.0.ZU;2-O
Abstract
The enthalpies of mixing In systems tri-n-butyl phosphate-diluent (hex ane-decane, carbon tetrachloride, benzene, toluene, and chloroform) we re determined calorimetrically at 298.15 K. The entropies of mixing in these systems were calculated on the basis of Gibbs excess energy dat a. The influence of the nature of the diluent on thermodynamic functio ns of mixing is discussed.