COPOLYMERIZATION OF OLEFINS IN A SERIES OF CONTINUOUS STIRRED-TANK SLURRY-REACTORS USING HETEROGENEOUS ZIEGLER-NATTA AND METALLOCENE CATALYSTS .1. GENERAL DYNAMIC MATHEMATICAL-MODEL

Authors
SOARES JBP HAMIELEC AE
Citation
Jbp. Soares et Ae. Hamielec, COPOLYMERIZATION OF OLEFINS IN A SERIES OF CONTINUOUS STIRRED-TANK SLURRY-REACTORS USING HETEROGENEOUS ZIEGLER-NATTA AND METALLOCENE CATALYSTS .1. GENERAL DYNAMIC MATHEMATICAL-MODEL, Polymer reaction engineering, 4(2-3), 1996, pp. 153-191
Citations number
33
Categorie Soggetti
Polymer Sciences","Engineering, Chemical
Journal title
Polymer reaction engineering → ACNP
ISSN journal
10543414
Volume
4
Issue
2-3
Year of publication
1996
Pages
153 - 191
Database
ISI
SICI code
1054-3414(1996)4:2-3<153:COOIAS>2.0.ZU;2-O
Abstract
A dynamic mathematical model for the copolymerization of olefins with Ziegler-Natta and metallocene catalysts in a series of continuous stir red-tank slurry-reactors was developed. The model accounts for the pre sence of multiple active site types and can be used to predict reactor productivity, molecular weight and copolymer composition averages.