INFLUENCE OF SUBSTITUENTS ON THE N K X-RAY-ABSORPTION NEAR-EDGE STRUCTURE OF PYRROLE DERIVATIVES

Authors
HENNIG C HALLMEIER KH BACH A BENDER S FRANKE R HORMES J SZARGAN R
Citation
C. Hennig et al., INFLUENCE OF SUBSTITUENTS ON THE N K X-RAY-ABSORPTION NEAR-EDGE STRUCTURE OF PYRROLE DERIVATIVES, SPECT ACT A, 52(9), 1996, pp. 1079-1083
Citations number
4
Categorie Soggetti
Spectroscopy
Journal title
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY → ACNP
ISSN journal
13861425
Volume
52
Issue
9
Year of publication
1996
Pages
1079 - 1083
Database
ISI
SICI code
1386-1425(1996)52:9<1079:IOSOTN>2.0.ZU;2-H
Abstract
The X-ray absorption and electron yield spectra of monomeric pyrrole i ncluding derivatives with different substituents, thiazole and oxazole have been investigated. Inductive and mesomeric effects on the spectr al features are discussed. Inductive effects create energy shifts of t he pi resonances; mesomeric effects cause a splitting and energy shif ts of the pi resonances.