Pc. Wang et al., INFLUENCE OF PAINT BAKING EXPOSURE ON THE LAP-SHEAR PROPERTIES OF A POLYMER-CORED LAMINATED STEEL, The Journal of adhesion, 50(4), 1995, pp. 233-247
Effect of thermal aging on the lap-shear properties of an acrylic-core
d laminated steel was investigated by shear testing of specimens follo
wing exposure in air to the paint bake temperature of 180 degrees C. T
he laminated steel consists of two thin steel layers bonded to a polym
er core. It was found that thermal aging caused an increase in shear m
odulus and a decrease in ductility. Shear strength initially decreased
, but then increased with aging time. Fractographic, thermal gravimetr
ic, and differential scanning calorimetric analyses indicated that the
decrease in shear strength and ductility is likely caused by void for
mation resulting from evaporation of the volatiles in the acrylic. The
se voids increased the local stresses. The subsequent increase in shea
r strength is attributed to the increase in adhesive cross-linking fro
m thermal curing which hardens the adhesive. The increase in shear mod
ulus with increase in aging time is ascribed primarily to thermal curi
ng.