Gs. Summy et al., COMPLETE DETERMINATION OF ATOMIC STATES BY PHOTON MOMENTUM-TRANSFER, Journal of physics. B, Atomic molecular and optical physics, 29(12), 1996, pp. 2607-2628
In this paper we present a theory which shows that the optical force o
n atoms due to spontaneous processes depends upon the quantum state of
the atom at the time it begins interacting with the optical field. Th
e momentum is treated as a classical variable and the theory used to m
odel the interaction between the atom and radiation is based on a quan
tum electrodynamic technique. The formalism developed is quite general
and, in principle, can be applied to the determination of initial ato
mic states prepared by a variety of mechanisms. An example of an appli
cation of the spontaneous force is presented which shows how it is pos
sible to use the momentum absorbed by an atom from a coherent light fi
eld to determine the density matrix of the atomic state created by a c
ollision process. For completeness, the derivation of a stimulated for
ce model is included where it is shown that the resulting force on ato
ms also depends on their initial state.