S. Baluja et Bm. Shukla, EFFECT OF ELECTRIC-FIELD ON TRACER-DIFFUSION OF I-131(-) IONS IN AGAR-GEL, Journal of the Indian Chemical Society, 73(6), 1996, pp. 233-237
The tracer-diffusion coefficient and mobility of I-131(-) ions in 2.5%
agar gel containing sodium nitrate, potassium nitrate, sodium sulphat
e and potassium sulphate solutions (0.001 M) have been determined at 2
5 degrees by zone electromigration in presence of d.c. field of differ
ent intensities. A non-Gaussian distribution of I-131(-) ion in d.c. f
ield resulted in two unequal values of tracer-diffusion coefficients D
-1 and D-2 in and against the field direction, which Increases with in
crease in intensity and duration of held application. A suitable mecha
nism is suggested to explain the observed results.