Citation
A. Biehl et al., REACTIONS OF PENTAFLUOROBENZENESULFANYLAMINES (C6F5S)(N)NH3-N, N=1,2,3 AND THE STRUCTURE OF (C6F5S)(3)N, Zeitschrift fur anorganische und allgemeine Chemie, 622(7), 1996, pp. 1263-1268
Citations number
26
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur anorganische und allgemeine Chemie
ISSN journal
00442313
→ ACNP
Volume
622
Issue
7
Year of publication
1996
Pages
1263 - 1268
Database
ISI
SICI code
0044-2313(1996)622:7<1263:ROP(N>2.0.ZU;2-P
Abstract
The crystal structure of (C6F5S)(3)N has been examined. The compounds
(C6F5S)(2)NX, X = SiMe(3) and 1/2 Hg have been prepared from (C6F5S)(2
)NH and characterised. In a number of other reactions, such as oxidati
on and irradiation, the S-N bond in (C6F5S)(2)NH was readily fractured
, forming the disulfide, (C6F5S)(2). The compound (C6F5S)(3)N has been
found to be unreactive. Details of the mass and C-13 NMR spectra of (
C6F5S)(n)NH3-n, n = 1, 2, 3 are reported.