ON THE SYSTEM ZN MO/O .1. PHASES AND PROP ERTIES OF TERNARY ZINC MOLYBDATES - CRYSTAL-STRUCTURE OF ZN3MO2O9/

Authors
SOHNEL T REICHELT W OPPERMANN H MATTAUSCH H SIMON A
Citation
T. Sohnel et al., ON THE SYSTEM ZN MO/O .1. PHASES AND PROP ERTIES OF TERNARY ZINC MOLYBDATES - CRYSTAL-STRUCTURE OF ZN3MO2O9/, Zeitschrift fur anorganische und allgemeine Chemie, 622(7), 1996, pp. 1274-1280
Citations number
25
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur anorganische und allgemeine Chemie
ISSN journal
00442313 → ACNP
Volume
622
Issue
7
Year of publication
1996
Pages
1274 - 1280
Database
ISI
SICI code
0044-2313(1996)622:7<1274:OTSZM.>2.0.ZU;2-5
Abstract
Several ternary compounds are known in the Zn/Mo/O-system. The phases ZnMoO4, Zn2Mo3O8 and Zn3Mo2O9 are stable at 900 degrees C. The coexist ence ranges are shown in the ternary phase diagram. The structure of Z n3Mo2O9 has been determined by single crystal X-ray diffraction. The c ompound crystallizes in the monoclinic space group P2(1)/m (a = 7,757( 1) Angstrom, b = 7,132(1) Angstrom, c = 8,370(2) Angstrom, beta = 117, 40(1)degrees, Z =2).