The relative humidity in a small space with a certain amount of hygros
copic material will stay constant because of sufficient moisture adsor
ption or desorption of these materials with temperature changes. To cl
arify this mechanism, fifteen kinds of hygroscopic composites composed
of wood meals, calcium silicate, and moisture-adsorbing synthetic pol
ymers were prepared. The relative humidity changes in this small space
containing these composites were measured for temperature changes of
the surrounding air. Humidity control efficiencies (HCEs) of these com
posites were calculated from equilibrium humidities. The HCEs of wood
meal composites proved to be equal or a little more than that of untre
ated wood veneer. Because it was supposed that humidity control proper
ties were affected by the hygroscopicities of the materials, the relat
ionships between the slopes of adsorption isotherms and the HCEs of th
e hygroscopic composites were investigated in relation to the weights
of the materials per spacial air volumes. As a result, the HCEs could
be expressed as logarithmic functions. It was suggested that the HCEs
of composites at equilibrium humidities could be predicted from the ad
sorption isotherms. The results obtained are not only useful in design
ing hygroscopic composites but also are applicable to the finish or th
e overlay of an interior wall.