Lk. Montgomery et al., CHARACTERIZATION OF THE ELECTROCRYSTALLIZATION PRODUCTS OF BIS(ETHYLENEDITHIO)TETRASELENEFULVALENE (BETS) AND TETRABUTYLAMMONIUM TETRACHLOROGALLATE, Molecular crystals and liquid crystals science and technology. Section A, Molecular crystals and liquid crystals, 284, 1996, pp. 73-84
Nine different crystal morphologies have been isolated from the electr
ocrystallization products of bis(ethylenedithio)tetraselenafulvalene (
BETS) and tetrabutylammonium tetrachlorogallate. The morphologies have
been examined by X-ray crystallography and electrical transport measu
rements and have been assigned to several different crystal systems: k
appa-, lambda-, and kappa'-(BETS)2GaCl(4), alpha-(BETS)(3)GaCl4 . TCE,
and an incompletely characterized semiconductor. In experiments desig
ned to gain some understanding of the variable resistive superconducti
ng transition temperatures (T-c) in lambda-(BETS)(2)GaCl4, the influen
ce of gold paste on the AC susceptibility T-c was examined: gold paste
raises the onset of superconductivity, and the effect is reversible.
In related studies, it was found that isotropic pressure lowers T-c in
lambda-(BETS)(2)GaCl4 by -0.31 K/kbar. These observations are discuss
ed.