N. Kushch et al., MOLECULAR-COMPOUNDS EXHIBITING COUPLED CONDUCTING AND MAGNETIC-PROPERTIES AND BASED ON (CATION)(N)[M(DMIT)](2) AND (BETS)(2)(ANION) SALTS, Molecular crystals and liquid crystals science and technology. Section A, Molecular crystals and liquid crystals, 284, 1996, pp. 247-258
A systematic study has been carried out on a range of metal complexes
of the type (cation)(n)[M(dmit)(2)] (cation = NH(y)R(4-y); y = 1 or 2;
n = x, 1, 2; R = ethyl, propyl or butyl, or cation = organic radical
cations containing one or two TTF moieties; M = Ni or Pd and dmit = 2-
thioxo-1,3-dithiole-4,5-dithiolato). The synthesis of these complexes,
the crystal structure of (NHBu(3))(2)[Ni(dmit)(2)] and neutral [Ni(dm
it)(2)], their solution redox behaviour and the solid state conductivi
ties of the non-integer oxidation state compounds obtained by electroc
rystallization techniques are presented. Synthesis, structure and prop
erties of new compounds of the family of (BETS)(2)(anion) compounds wi
th (CuxCly)(n-) and[(FeCl4)(1-x)(GaCl4)(x)](-) anions are described.