SYNTHESIS, CRYSTAL-STRUCTURE AND PHYSICAL-PROPERTIES OF CHARGE-TRANSFER COORDINATION COMPLEX, [PT(H(2)DAG)(HDAG)][NI(DMIT)(2)]CENTER-DOT-1 2H(2)O-CENTER-DOT-CH3CN-CENTER-DOT-CH3OH/

Authors
YAMASHITA M ICHIKAWA A HAMA T OHISHI T MANABE T MIYAMAE H YOSHIDA D SUGIURA S KITAGAWA H IWASA Y MITANI T
Citation
M. Yamashita et al., SYNTHESIS, CRYSTAL-STRUCTURE AND PHYSICAL-PROPERTIES OF CHARGE-TRANSFER COORDINATION COMPLEX, [PT(H(2)DAG)(HDAG)][NI(DMIT)(2)]CENTER-DOT-1 2H(2)O-CENTER-DOT-CH3CN-CENTER-DOT-CH3OH/, Molecular crystals and liquid crystals science and technology. Section A, Molecular crystals and liquid crystals, 284, 1996, pp. 391-398
Citations number
10
Categorie Soggetti
Crystallography
Journal title
Molecular crystals and liquid crystals science and technology. Section A, Molecular crystals and liquid crystals → ACNP
ISSN journal
1058725X
Volume
284
Year of publication
1996
Pages
391 - 398
Database
ISI
SICI code
1058-725X(1996)284:<391:SCAPOC>2.0.ZU;2-B
Abstract
A low-dimensional charge transfer coordination complex, [Pt(H2dag)(Hda g)] [Ni(dmit)2].1/2H2O.CH3CN.CH3OH (H2dag=diamino-glyoxime; dmit-1,3-d ithiol-2-thione- 4,5-dithiolate) has been synthesized. In the crystal, [Pt(H2dag)(Hdag)] molecules and [Ni(dmit)2] molecules are dimerized, respectively, and the dimerized molecules are stacked alternatively, f orming a linear chain structure. The intermolecular S...S contacts bet ween [Ni(dmit)2] molecules in the neighboring linear chains are observ ed, and moreover intermolecular hydrogen-bonds between S of dmit and H of dag ligands in the neighboring linear chains are also observed, re sulting in the two-dimensional network. Single-crystal electrical cond uctivity, absorption spectrum and magnetic susceptibility have been me asured and their results are discussed.