MATHEMATIC MODELING OF THE PECULIARITIES OF NO DECOMPOSITION ON RH(111)

Authors
MAKEEV A SLINKO MM
Citation
A. Makeev et Mm. Slinko, MATHEMATIC MODELING OF THE PECULIARITIES OF NO DECOMPOSITION ON RH(111), Surface science, 359(1-3), 1996, pp. 467-472
Citations number
13
Categorie Soggetti
Chemistry Physical
Journal title
Surface science → ACNP
ISSN journal
00396028
Volume
359
Issue
1-3
Year of publication
1996
Pages
467 - 472
Database
ISI
SICI code
0039-6028(1996)359:1-3<467:MMOTPO>2.0.ZU;2-Q
Abstract
The complicated reaction kinetics of NO desorption and decomposition w ere adequately simulated within the framework of a deterministic model considering interactions in the adsorbed layer. The repulsive interac tions between N and NO adparticles together with the strong inhibition of NO dissociation by NO, N and O adsorbates were shown to be respons ible for the peculiarities of N-2 and NO TPD spectra from the Rh(111) surface.