AN ASYMMETRIC-SYNTHESIS OF ALPHA-AMINO-ACID DERIVATIVES FROM RACEMIC ETHYL N-PHENYLSULFONYL-ALPHA-BROMOGLYCINATE USING HOMOCHIRAL ALUMINUM COMPLEXES

Authors
MORGAN PE WHITING A MCCAGUE R
Citation
Pe. Morgan et al., AN ASYMMETRIC-SYNTHESIS OF ALPHA-AMINO-ACID DERIVATIVES FROM RACEMIC ETHYL N-PHENYLSULFONYL-ALPHA-BROMOGLYCINATE USING HOMOCHIRAL ALUMINUM COMPLEXES, Tetrahedron letters, 37(27), 1996, pp. 4795-4796
Citations number
8
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
37
Issue
27
Year of publication
1996
Pages
4795 - 4796
Database
ISI
SICI code
0040-4039(1996)37:27<4795:AAOADF>2.0.ZU;2-S
Abstract
Reactions of a racemic alpha-bromoglycinate 2 with readily available a lkyl aluminium reagents modified by binaphthol derivatives produce a-a mino acid analogues 3 in high yields and with asymmetric induction of up to 62%. Copyright (C) 1996 Elsevier Science Ltd