Angle-integrated and angle-resolved (AR) photoelectron spectroscopy (P
ES) experiments were performed on GaAs(001) 2 x 4 Sb surfaces. The res
ults of angle-integrated PES show that only Sb atoms lie on the GaAs s
urface and that they bond to Ga atoms. ARPES experiments revealed a su
rface state whose dispersion is very similar to the As dimer dangling
bond surface stare of As-terminated GaAs(001). These results suggested
that Sb dimers terminate GaAs surfaces and bond to Ga atoms of the se
cond top atomic layer.