STRUCTURAL EVIDENCE FOR THE OXATHIOLIUM CATION - SYNTHESIS AND STRUCTURE OF 3,5-DI-TERT-BUTYL-1,2-OXATHIOLIUM AQUATETRACHLORO-OXOMOLYBDATE(V)

Authors
CINDRIC M MATKOVICCALOGOVIC D KAMENAR B
Citation
M. Cindric et al., STRUCTURAL EVIDENCE FOR THE OXATHIOLIUM CATION - SYNTHESIS AND STRUCTURE OF 3,5-DI-TERT-BUTYL-1,2-OXATHIOLIUM AQUATETRACHLORO-OXOMOLYBDATE(V), Inorganica Chimica Acta, 248(1), 1996, pp. 103-106
Citations number
17
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganica Chimica Acta → ACNP
ISSN journal
00201693
Volume
248
Issue
1
Year of publication
1996
Pages
103 - 106
Database
ISI
SICI code
0020-1693(1996)248:1<103:SEFTOC>2.0.ZU;2-G
Abstract
Reaction of molybdenum (V) chloride with thiodipivaloylmethane results in the title complex [C11H19OS] [MoOCl4(OH2)], the first solid state structural example containing the 3,5-di-tert-butyl-1,2-oxathiolium sp ecies. The aquatetrachloro-oxomolybdate (V) anion is mononuclear with the molybdenum atom in a distorted octahedral coordination. The comple x was characterised by chemical analysis, IR and ESR spectra, and X-ra y crystallography. It crystallises in the monoclinic system, space gro up P2(1)/n with a = 11.826(4), b = 9.831(3), c = 16.851(5) Angstrom, b eta = 101.20(3)degrees, Z = 4.