Composites are used as an esthetic restorative material in prosthetic
dentistry, often with a metallic substructure that provides support wh
en large restorations are required. Different bonding systems have bee
n proposed to occupy the gap between the composite and metal and to re
duce marginal leakage at this interface, which with time results in a
degradation of the metal-composite junction with dissociation of these
two materials. This study compared two methods of adhesion of composi
te to metal: (1) the Silicoater, based on a silanization of metal and
(2) the Spectralink, based on an ionization of metal. A total of 108 m
etal pellets were covered with composite; 36 pellets formed the baseli
ne or control group and 72 pellets were placed on temporary fixed part
ial dentures for the 12 patients in the study. The two bonding methods
were compared at 0, 30, and 90 days, Marginal leakage (<0.7 mu m) and
marginal gap (<0,6 pm) for the baseline groups were minimal and demon
strated no significant difference between the two samples. The degrada
tion of marginal adaptation and hermeticity was faster and more severe
with the pellets of the ionization sample. The Silicoater samples exh
ibited a better hydrolytic resistance with the formation of a hydropho
bic polymer. The degradation of the composite-metal interface with the
Spectralink method appeared to be the result of the hydrophilic chara
cter of polyfluoromethacrylate. Nevertheless, the values of the margin
al gap (<6.0 mu m) and the microleakage (<30.0 mu m) remained low for
the metal treatments.