The incorporation of hydrogen in polycrystalline silicon (poly-Si) is
essential to improve the materials properties which contains a high de
nsity of localized states in the grain-boundary regions. The presence
of hydrogen in poly-Si gives rise to new and hitherto unexpected pheno
mena. In this paper, light-induced defect creation and H-induced metas
table changes of the dark conductivity are reviewed. Experimental evid
ence is presented which demonstrates the direct participation of H in
the metastable effects.