R. Somatri et al., ALPHA-BACKSCATTERING USED IN STOICHIOMETRY DETERMINATION OF THIN SIC COATINGS ON SI(100) WAFERS, Nuclear instruments & methods in physics research. Section B, Beam interactions with materials and atoms, 113(1-4), 1996, pp. 284-287
Monocrystalline cubic silicon carbide (beta) is a very interesting sem
iconductor material because of its wide band gap (2.3 eV). In order to
reduce the density of defects in epitaxially grown SiC, a buffer laye
r obtained by reactive chemical vapour deposition (RCVD) was grown on
the Si(100) wafer. We present the results of the analysis of such buff
er layers. Alpha backscattering spectrometry was used to determine the
carbon depth profiles. It was performed at a 4.3 MeV incident energy
in order to take advantage of the 4.26 MeV C-12(alpha, alpha)C-12 reso
nance. The cross sections of He-4 scattering on both carbon and silico
n, which are required in the analysis were measured. The depth resolut
ion, the sensitivity and the accuracy of the backscattering analysis a
re discussed together with infrared spectrometry data. The results all
ow to optimize the RCVD parameters, especially the temperature and the
dilution ratio H-2/C3H8.