The response of a quadrupolar spin system in zero applied magnetic fie
ld to a long rf pulse, for both single crystal and polycrystalline sam
ples possessing broad Lorentzian:shaped resonance lines has been studi
ed. The dependencies of magnetization on frequency offset, linewidth a
nd power are investigated both theoretically and experimentally. The p
roblem of the effective field direction in both single crystal and pol
ycrystalline samples is also discussed. For a polycrystalline cuprous
oxide (Cu2O) sample it is observed that the magnetization after a long
pulse in on-resonance condition does not become zero for time t much
greater than T-2, in agreement with theoretical results. It has also b
een shown that the magnetization increases with increase in the width
of the resonance line as well as with the decrease in the excitation p
ower.